(1'Z)-Dechloromycorrhizin A
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| Category | Antibiotics |
| Catalog number | BBF-02015 |
| CAS | 161815-17-4 |
| Molecular Weight | 248.27 |
| Molecular Formula | C14H16O4 |
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Description
(1'Z)-Dechloromycorrhizin A is an antibiotic produced by Lachnum papyraceum. It has weak anti-gram-positive bacteria, yeast, and mold activity, and has a strong nematicidal effect.
Specification
| Synonyms | (1'Z)-dechloromycorrhizin |
| Storage | Store at -20°C |
| IUPAC Name | (1aR,3aS,7aS)-3a-hydroxy-2,2-dimethyl-5-[(Z)-prop-1-enyl]-1,1a-dihydrocyclopropa[c][1]benzofuran-4,7-dione |
| Canonical SMILES | CC=CC1=CC(=O)C23CC2C(OC3(C1=O)O)(C)C |
| InChI | InChI=1S/C14H16O4/c1-4-5-8-6-10(15)13-7-9(13)12(2,3)18-14(13,17)11(8)16/h4-6,9,17H,7H2,1-3H3/b5-4-/t9-,13-,14+/m0/s1 |
| InChI Key | PIKQVDHHJWKTME-MWXCKUNPSA-N |
Properties
| Appearance | Light Yellow Oil |
| Antibiotic Activity Spectrum | Gram-positive bacteria; yeast; parasites |
| Boiling Point | 421.3±45.0°C at 760 mmHg |
| Density | 1.3±0.1 g/cm3 |
Reference Reading
1. Natural Products of Picea Endophytes from the Acadian Forest
David R McMullin, Blake D Green, Natasha C Prince, Joey B Tanney, J David Miller J Nat Prod. 2017 May 26;80(5):1475-1483. doi: 10.1021/acs.jnatprod.6b01157. Epub 2017 Apr 11.
Endophytes of healthy needles were collected from Picea rubens (red spruce) and P. mariana (black spruce) in a survey of southeastern New Brunswick, Canada. Four endophyte strains were selected for further investigation based on the production of biologically active extracts from culture filtrates during screening as well as phylogenetic relationship to species known to produce natural products or taxonomic novelty. A novel endophyte within the family Rhytismataceae produced two new dihydropyrones (1 and 2) as major metabolites together with phthalides (3 and 4), isocoumarins (5 and 6), and tyrosol (7). Lachnum cf. pygmaeum synthesized a new chlorinated para-quinone, chloromycorrhizinone A (8), and the nematicidal compounds (1'Z)-dechloromycorrhizin A (9), mycorrhizin A (10), and chloromycorrhizin A (11). A new isocoumarin (12) and four related structures (13-16) were isolated from an undescribed taxon in the Mycosphaerellaceae. The known antifungal metabolites cryptosporiopsin (17), 5-hydroxycryptosporiopsin (18), (+)-cryptosporiopsinol (19), and mellein (20) were produced by Pezicula sporulosa. Phylogenetically diverse conifer endophytes from the Acadian forest continue to be a productive source of new biologically active natural products.
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Bio Calculators
* Our calculator is based on the following equation:
Concentration (start) x Volume (start) = Concentration (final) x Volume (final)
It is commonly abbreviated as: C1V1 = C2V2
* Total Molecular Weight:
g/mol
Tip: Chemical formula is case sensitive. C22H30N4O √ c22h30n40 ╳
