3',4'-Dideoxy-3'-eno-ribostamycin

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Category Antibiotics
Catalog number BBF-01360
CAS 78788-31-5
Molecular Weight 420.46
Molecular Formula C17H32N4O8

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Description

3',4'-Dideoxy-3'-eno-ribostamycin is produced by the strain of Streptomyces ribosidi-ficus AF-1 (PERM-P 2131). It has anti-gram positive bacteria and negative bacteria activity.

Specification

Synonyms BRN 5163215; 3,5-Diamino-2-{[3-amino-6-(aminomethyl)-3,4-dihydro-2H-pyran-2-yl]oxy}-6-hydroxycyclohexyl pentofuranoside
IUPAC Name 2-[3,5-diamino-2-[[3-amino-6-(aminomethyl)-3,4-dihydro-2H-pyran-2-yl]oxy]-6-hydroxycyclohexyl]oxy-5-(hydroxymethyl)oxolane-3,4-diol
Canonical SMILES C1C=C(OC(C1N)OC2C(CC(C(C2OC3C(C(C(O3)CO)O)O)O)N)N)CN
InChI InChI=1S/C17H32N4O8/c18-4-6-1-2-7(19)16(26-6)28-14-9(21)3-8(20)11(23)15(14)29-17-13(25)12(24)10(5-22)27-17/h1,7-17,22-25H,2-5,18-21H2
InChI Key HJWXBBYTSANIQZ-UHFFFAOYSA-N

Properties

Antibiotic Activity Spectrum Gram-positive bacteria; Gram-negative bacteria
Boiling Point 689.3°C at 760 mmHg
Melting Point 243-246°C
Density 1.49 g/cm3

Reference Reading

1. White-light emission in Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-doped α-NiMoO4nanoparticles
Schindra Kumar Ray, Bhupendra Joshi, Jin Hur Nanotechnology. 2022 Jul 8;33(39). doi: 10.1088/1361-6528/ac74cd.
Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-dopedα-NiMoO4nanoparticles were synthesized using a microwave hydrothermal method and studied for white-light emission under 980 nm laser diode excitation. White upconversion (UC) light was successfully obtained with the appropriate control of blue, green, and red emissions by successfully tuning the Er3+and Ho3+concentrations in Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-dopedα-NiMoO4, respectively. In addition, the white color emission was shown by the CIE chromaticity coordinates of samples. The energy transfer mechanisms are explained in detail based on the emission spectra and pump power density-dependent UC luminescence intensity in rare earth (Yb3+/Er3+/Tm3+and Yb3+/Er3+/Tm3+/Ho3+)-dopedα-NiMoO4nanoparticles. The results indicate that Yb3+/Er3+/Tm3+- and Yb3+/Er3+/Tm3+/Ho3+-dopedα-NiMoO4nanoparticles can be good candidates for white-light devices.
2. 5-(3-Methoxy-pheneth-yl)-4-(2-methoxy-phen-yl)-4H-1,2,4-triazol-3-ol
Muhammad Hanif, Ghulam Qadeer, Nasim Hasan Rama, Wai-Yeung Wong Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 25;64(Pt 11):o2180. doi: 10.1107/S1600536808033990.
In the mol-ecule of the title compound, C(18)H(19)N(3)O(3), the triazole ring is oriented with respect to the 3-methoxy-phenyl and 2-methoxy-phenyl rings at dihedral angles of 11.79 (3) and 89.22 (3)°, respectively. The dihedral angle between the two benzene rings is 85.95 (3)°. In the crystal structure, inter-molecular O-H⋯N and C-H⋯O hydrogen bonds link the mol-ecules. There is a π-π contact between the triazole and 3-methoxy-phenyl rings [centroid-centroid distance = 3.916 (3) Å]. There is a π-π contact between the triazole and one of the 3-methoxy-phenyl rings [centroid-centroid distance = 3.916 (3) Å ]. C-H⋯π contacts are also found between the benzene ring and the methyl groups of their 3-methoxy-substituents.

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