Drechslerine D
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| Category | Others |
| Catalog number | BBF-04381 |
| CAS | 405157-88-2 |
| Molecular Weight | 250.34 |
| Molecular Formula | C15H22O3 |
| Purity | 95.0% |
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Description
Drechslerine D is a metabolite of the algicolous fungus Drechslera dematioidea.
Specification
| Synonyms | (1S,2R,6R,7R,8S)-1-Methyl-8-(1-hydroxy-1-methylethyl)-11-methylene-4-oxatricyclo[5.3.1.02,6]undecane-5-one; 4,8-Methano-1H-cyclohepta[c]furan-1-one, octahydro-7-(1-hydroxy-1-methylethyl)-4-methyl-9-methylene-, (3aR,4S,7S,8R,8aR)-rel-(-)- |
| Storage | Store at 2-8°C protect from light |
| IUPAC Name | (1R,2R,6R,7S,10S)-10-(2-hydroxypropan-2-yl)-7-methyl-11-methylidene-4-oxatricyclo[5.3.1.02,6]undecan-3-one |
| Canonical SMILES | CC12CCC(C(C1=C)C3C2COC3=O)C(C)(C)O |
| InChI | InChI=1S/C15H22O3/c1-8-11-9(14(2,3)17)5-6-15(8,4)10-7-18-13(16)12(10)11/h9-12,17H,1,5-7H2,2-4H3/t9-,10+,11+,12-,15+/m0/s1 |
| InChI Key | DFXRRWWJMJRDNJ-MVIRXUPPSA-N |
Properties
| Appearance | Oily Matter |
| Boiling Point | 384.0±35.0°C at 760 mmHg |
| Density | 1.1±0.1 g/cm3 |
| Solubility | Soluble in Ethanol |
Reference Reading
1. Total synthesis of the bicyclic marine sesquiterpenoid drechslerine B
Hisahiro Hagiwara, Masakazu Fukushima, Kimihiko Kinugawa, Takuya Matsui, Takashi Hoshi, Toshio Suzuki Nat Prod Commun. 2011 Mar;6(3):311-3.
The total synthesis of the recently isolated bicyclic sesquiterpenoid drechslerine B (2), isolated from the algicolous fungus Drechslera dematioidearare in the marine red alga Liagora viscida, has been achieved, starting from (S)-carvone (8), via an intramolecular aldol reaction and palladium-catalyzed carbon monoxide insertion as key reactions.
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Bio Calculators
* Our calculator is based on the following equation:
Concentration (start) x Volume (start) = Concentration (final) x Volume (final)
It is commonly abbreviated as: C1V1 = C2V2
* Total Molecular Weight:
g/mol
Tip: Chemical formula is case sensitive. C22H30N4O √ c22h30n40 ╳
